The porous sic substrates were characterized by measuring their porosity, pore size distribution, surface characteristics, and structure. In this paper, investigations of structure and morphology properties of n and ptype porous silicon layer prepared by photoelectrochemical etching pece and electrochemical etching ece were. A capacitive gas or humidity sensor using the adsorption of gases on the porous surface can be easily. In this work, the nanocrystalline porous silicon ps films is prepared by photoelectrochemical etching of ntype silicon wafer with different currents. Porous silicon is constituted by a network of pores immersed in a nanocrystalline matrix 15.
Porous silicon is a form of the chemical element silicon that has introduced nanopores in its. It was revealed the different dispersion of electrical capacitance in different frequency bands and the complex relaxation. Electroluminescent properties of porous silicon films. In this paper, we endeavor to cover applications of porous. Formation and properties fills a gap in the literature of the field today, providing a thorough introduction to current knowledge of the formation, processing, and properties of porous silicon. The optical properties of porous silicon are discussed in a wide spectral range from the infrared to the ultraviolet. Formation and application of porous silicon uni kiel. Using electrochemical etching, liquidphase doping, and hightemperature. Nano express open access effect of graphene oxide on the properties of porous silicon igor b. Photocatalytic properties of porous silicon nanowires. Porous silicon in the most basic sense,porous silicon is a network ofair holes within aninterconnected silicon matrix.
Photoelectrochemical properties of porous silicon based. Thermal conductivity and microstructure properties of. The chemistry of silicon and its compounds is extremely dynamic. Therefore, it can be surface modified to improve stability and cell attachment.
The surface of porous silicon may be modified to exhibit different properties. The structural, optical, and photoluminescence properties of porous silicon psititanium dioxide tio2 nanostructures were investigated. Porous sic ceramic were prepared with silicon carbide powder as the aggregate, silicone resin as the binder and pore agent by the process of mixing, isostatic pressure molding, and calcination. Photoluminescence properties of silica aerogelporous. Controlled morphology and optical properties of ntype. Cnts were deposited on porous silicon nanostructures psin at 750 0c on porous silicon by using doublefurnace thermal chemical vapor deposition technique. Osa the effect of silicon loss and fabrication tolerance.
Porous silicon has been the focus of much research activity in recent years, in view of its luminescence, which may enable light emitting devices to be integrated with silicon chips. Typical of morphological properties of porous silicon uday muhsin nayef1, mohammed waleed muayad 1,2department of applied science university of technology, baghdad iraq. Luminescence properties of porous silicon request pdf. Porous silicon interfaces have been modified with nitrided tio2 nanoparticles. They were trying to develop an electrochemical method to machine silicon wafers for use in microelectronic circuits. Chapter 2 fundamentals of porous silicon and applications. A method for the fabrication of highly reproducible, monodisperse, mesoporous silicon particles with controlled physical characteristics through electrochemical etching of patterned silicon trenches is. Pdf structural, morphological, chemical and optical properties of. Effect of thermal annealing on the properties of porous. In this paper, we investigate the effect of nonuniformities enlargement of current passage, nonequal surface current densities, etc. We have studied the thermoelectric properties of porous silicon, a nanostructured, yet singlecrystalline form of silicon. However, research into its properties has yielded the possibility of diverse novel applications see below.
Many applications of porous silicon psi emerged because of the its rare properties, it has been used in optical. Request pdf ferroelectric properties of porous silicon silicon compatible ferroelectric random access memory ram has come a step closer with the synthesis of porous silicon that exhibits. The physical properties of porous silicon are fundamentally determined by the shape, diameter of pores, porosity, and the thickness of the formed porous layer. The ability to tailor the physicochemical properties of porous silicon at the micro.
Mechanical properties of porous silicon springerlink. Typical of morphological properties of porous silicon. Porous silicon is identical to the silicon used in many technological applications today with the difference that the surface contains tiny pores, ranging from less than 2 nm to microns, capable of absorbing and emitting light. Properties of porous siliconnitride materials springerlink. These parameters include hf concentration, current density, anodization time, and silicon wafer type and resistivity. The photoluminescence of nanocomposites is characterized by a redorange band related to silicon nanoparticles and a. The influence of gamma irradiation on the chemical and.
Effect of graphene oxide on the properties of porous silicon. Crosssectional sem micrographs of various porous silicon structures formed by anodic etching 6. The exceptional plasticity recorded for individual silicon nanowires is yet to be demonstrated in mesoporous silicon. Uhlir at bells laboratories in usa 1, when they were doing electrolytic shaping the surface of silicon and germanium. In this paper, porous silicon layers was prepared from ptype silicon with. The properties of porous sic ceramics were investigated as a function of sic content. A number of application areas are highlighted that rely heavily on the mechanical properties of porous silicon. The aim of this work is to present the superconducting properties of nb thin. Porous silicon shows some interesting features for micromechanical applications. Silicon carbide sic porous substrates are prepared by pressureless sintering of sic powders under an inert atmosphere of argon.
Request pdf luminescence properties of porous silicon we report the results of a systematic study of the influence of the anodization and etching conditions, and chemical and thermal. Their transport characteristics were investigated using n2 and he as the test gases. Porous silicon carbide sintered substrates for high. The results have been compared with the porous structures fabricated by means of. It is well known that crystallites size the optical properties of porous silicon. Structural and optical properties of n type porous silicon effect of. The resulting porous silicon nanowires exhibit a large surface area of 337 m2 g. Optical properties of porous silicon sciencedirect. Yarytska5 abstract we studied an effect of the graphene oxide go layer on the optical and electrical properties of porous silicon ps. Porous silicon because of its unique properties of spatial confinement, dimensionality large active and decrease of reflection losses, etc. I think it is now quite timely for a book such as this to appear. Photoluminescence of porous silicon prepared by chemical etching method 228 experimental the porous silicon was fabricated by using the light doped ptype silicon wafer, where the dopant was boron. The composition of the surface and electrical properties of silicon oxide nanocomposites of porous silicon were investigated by ftir spectroscopy in the range of 400 4000 cm1 and by impedance spectroscopy in the frequency range of 25 hz 1 mhz.
Porous silicon carbide ceramics with high open porosity and large pore size are usually m an u applied as filters for the cleaning of hot dust gases. Structural and optical properties of n type porous silicon effect of etching time. Align carbon nanotubes with diameters of 15 to 30 nm were successfully. Depending on the etching parameters, for example, current density, hf concentration, or substrate doping type and level, the physical properties of ps can be varied. The anodization parameters that influence on the final characteristics of the fabricated layers are also discussed and the porous silicon photoluminescence is. Poco perfected a unique, proprietary process for producing silicon carbide that is different from conventional silicon carbides, the properties and characteristics of which are outlined in this document. The structural properties of carbon nanotubes grown on. Ferroelectric properties of porous silicon request pdf. In the flame, the primary particles fuse into larger units, called aggregates, with sizes from about 150 to 500 nm. Porous silicon nanowires are synthesized by metal assisted wetchemical etching of highlydoped silicon wafers. It also analyzes present and potential applications of porous silicon in. In this paper, carbon nanotubes on porous silicon substrate were developed in order to get high quality nanotubes for various kind of application.
Luminescence of porous silicon in the infrared the properties of the primary band are explained in terms of a quantumsize model for formation of porous silicon, porous silicon, edited by zhe chuan feng et al. Preparation and photoluminescence properties of porous silicon. Fabrication of photoluminescent ntype porous silicon nps, using electrodeassisted lateral electric field accompanied with a perpendicular magnetic field, is reported. Often, freshly etched porous silicon may be unstable due to the rate of its oxidation by the atmosphere or unsuitable for cell attachment purposes. Preparation and properties of porous silicon carbide based.
Electroluminescent properties of porous silicon films under electrochemical oxidation volume 256 s. The importance of a number of fabrication issues in determining properties is now established and should lead to material of improved quality. Psi structures consisting of macro and mesoporous layers were fabricated by metalassisted chemical etching, and then tio2 was introduced inside the psi matrix using the atomic layer deposition technique. This work comprises over 50 commissioned essays on the subject from scientists in europe, america and japan. Porous silicon psi has been produced in this work by photoelectrochemical pec etching process. The material is a complicated network of silicon threads of thicknesses that range from 2 to 5 nm. Porous silicon layers psi were prepared from ptype silicon wafer by using electrochemical cell with etching time 20 min, current 30 ma and fixed electrolyte solution hf. There are many preparation methods of porous siliconps, such as electrochemical etchingece, photochemical etching, chemical etching and so on. Variation of the nanostructural and optical variation of the nanostructural and optical features of porous silicon with ph conditions w. Pdf photoluminescence properties of porous silicon.
Properties and characteristics of silicon carbide preface poco graphite, inc. The irradiation has been achieved using diode laser of 2 w power and 810 nm wavelength. The addition of c to sic decreased the electrical resistivity, thermal conductivity, and compressive strength of the porous sic ceramics for an increase in c content from 0 to 50 wt%. Ece, also known as anodic etching, is more common among these methods. Effects of carbon and silicon on electrical, thermal, and. However, the large porosity and large pore size will decrease the mechanical properties. Silicon carbide sic porous ceramics with a hybrid reaction bond can withstand higher temperatures than traditional glassbonded porous ceramics. Tailoring the structural, optical, and photoluminescence. The beauty of the porous silicon process is that depending on the mix of chemistry and levels of applied current, the pores or porous surface can be finely tuned altering the refractive index, volume density, surface area and overall porosity from a bulk silicon wafer to a silicon sponge layer or all the way to a silicon cloud or web. One prominent example of this can be seen in the interaction of porous silicon with living cells, which can be totally unwilling to settle on smooth silicon surfaces but readily adhere to porous silicon, giving rise to great hopes for such future applications as programmable drug delivery or advanced, braincontrolled prosthetics. Photoluminescence properties of porous silicon nanocomposites h. Some applications make use of its high surfacetovolume ratio. Porous silicon is a very promising material due to its excellent mechanical and thermal properties, its obvious compatibility with siliconbased microelectronics 17 and its low cost.
Photoluminescence, morphological and electrical properties of. Effect of silicon crystal size on photoluminescence. Transformation of porous silicon into oxidized porous silicon porous silica modifies of course the physical characteristics and optical properties of porous silicon layer 2 3,and also allow. Chemical, morphological and electrical properties of porous silicon. The size of these air holes,called pores, can vary from afew nanometers to a fewmicrons depending onthe conditions of formation andthe characteristics of thesilicon. Rahul gupta, 20367585 porous silicon annealing analysis effect of thermal annealing on the properties of porous silicon rahul gupta 20367585 school of mechanical engineering, university of western australia supervisor. Photoluminescence properties of porous silicon nanocomposites. Pdf on jan 1, 1997, leigh canham and others published properties of porous silicon find, read and cite all the research you. Preparation and properties of nanocomposites of silicon.
1213 1183 815 1135 239 380 1280 403 1055 1432 1610 1247 1229 119 255 1389 1196 499 182 882 767 1352 231 1011 1118 547 47 178 670 1116 1615 1530 1537 998 66 134 579 846 37 136 1145 1113 659